Origin of SMM behaviour in an asymmetric Er(III) Schiff base complex: a combined experimental and theoretical study.
نویسندگان
چکیده
An asymmetric erbium(III) Schiff base complex [Er(HL)2(NO3)3] was synthesized which shows SMM behaviour with an Ueff of 5.2 K. Dipolar interaction in 1 significantly reduced upon dilution which increases the barrier height to 51.5 K. Ab initio calculations were performed to shed light on the mechanism of magnetization relaxation.
منابع مشابه
Origin of SMM behaviour in asymmetric Er(III) Schiff base complex: A combined experimental and theoretical study
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 28 شماره
صفحات -
تاریخ انتشار 2015